Quantification of lithium inventory loss in micro silicon anode via titration-gas chromatography
نویسندگان
چکیده
The commercialization of silicon as an anode material for lithium-ion batteries has been largely impeded by its severe volume changes during cell operation, causing continuous loss Li inventory. As such, it is vital to understand and quantify the sources capacity fade in order design effective mitigation strategies. Herein, we a method based on Titration Gas Chromatography (TGC) reveal non-linear expansion ?Si lithiation process. towards end leads accelerated SEI formation conductive pathway loss, resulting large amount trapped Li–Si alloy accumulation. TGC also applied investigate anodes with two different binders: Sodium Carboxymethyl Cellulose (CMC-Na) Polyacrylic Acid (PAA). primary reason CMC-Na binder alloy, which can be mitigated using more robust PAA binder. Sate Charge (SoC) control principle investigated ?Si-LFP full cells both binders tuning N/P ratios (1.5–3). results indicate robustness crucial mitigating accumulation anode.
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ژورنال
عنوان ژورنال: Journal of Power Sources
سال: 2022
ISSN: ['1873-2755', '0378-7753']
DOI: https://doi.org/10.1016/j.jpowsour.2022.231327